Single-Crystal X-Ray Structural Analysis and Electronic Structures Calculation of Rare Sugar
Bui Quoc Huy, Tomohiko Ishii, Norito Taniguchi, Natsumi Nagayama, Genta Sakane
Department of Advanced Materials Science, Faculty of Engineering, Kagawa University Hayashi-cho, Takamatsu, Kagawa 761-0396, JAPAN.
Department of Chemistry, Faculty of Science, Okayama University of Science 1-1 Ridaicho, Kita-ku, Okayama 700-0005,JAPAN
Abstract
There are two types of mono-saccharide sugars in nature, which are natural monosaccharide and rare sugar. The sugar that exists in extreme few amount in nature is called as rare sugar e.g. D-psicose, D-allose. The reasons we choose the rare sugar as a research target are because the rare sugar has almost no calories and is very useful for diabetic and dieter patients. Specifically, D-psicose is a no-calorie rare sugar with the sweetness of about 70 % of a sucrose. It has been confirmed that taking the D-psicose with meals suppresses the rise of sugar into the blood. Further, it is very effective in improving and preventing the diabetes. In order to investigate a research on the rare sugars, the first step must be to obtain the correct molecular structure. However, few crystal structures of rare sugars have been reported up to now. Therefore, the purpose of this research is to analyze the single-crystal X-ray structure of unknown rare sugar -L-glucose-. In addition , the DV-Xαmolecular orbital method is used to compare the differences in a hydrogen bonding between D-glucose and L-glucose, and to make a novel supramolecular rare sugar.
Keywords: Rare Sugar, D-psicose, L-glucose, Supramolecule, Hydrogen bonding.
Topic: DV-Xa Method