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The understanding of students in the process of forming covalent bonds needs to be overcome by using interactive media. For this reason, research has been carried out using a Design-Based Research (DBR) method. The stages of this study consisted of wall analysis and the development of trial design validation and feasibility tests. The overall validation test results were obtained from 0.80-0.96 and declared valid, while the feasibility test results obtained a percentage of feasibility 83.33-97.50%. The percentage shows that AR learning media in the formation of covalent bonds based on valence bond theory is worthy of being used as a learning medium.