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This research aims to develop E-learning on thermodynamics subject to increase analytical skill of students. E-learning can be accessed via computer or smartphone. Thermodynamics is a subject which learned the relationship between heat and work also properties that support those relationship. This research method used ADDIE method: Analyze, Design, Development, Implementation, and Evaluation. Research was conducted in Laboratory of Media State University of Jakarta for six months, from October 2018 to April 2019 with physics education students of State University of Jakarta as object of research. Students analitycal skill improvement test was conducted by pre-test and post-test in two classes (class A and class B). Analytical skill is an ability to identify, separate, and distinguish components or elements of a fact, concept, opinion, assumption, conclusion and to check every components to see whether there is a contradiction. Material expert validation results show 91,28%,media expert validation 91,11%,learning expert 91,85%. N-gain test show a score 0,67 (medium category) for class A and 0,5 (medium category) for class B. Conclusion of this research is developed E-learning can increase Analytical Skill of Students.