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This study aims to develop teaching material integration by spirit values through 4S TMD method. The research method used is development research by Richey-s and Klein-s consisting of design, development, and evaluation. This study was conducted until the step of design and development. The method of development teaching materials used is 4S TMD. This article is the first part of the development teaching materials that includes selection and structuration steps. At the selection step, an indicator is developed in accordance with the curriculum requirements, explaining the concept, and analyzing the spiritual value. Furthermore, in the structural step developed concept maps, macro structures and multiple representations. The results of the selection and structuring steps were evaluated by an expert lecturer in the chemical education department. The result of the two steps in this study produced a draft of teaching material integrated by spiritual values. Evaluation of the draft of teaching material has done by expert lecturers in the field of chemical education.