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Removal Phospate-containing Detergent Wastewater by Mg-Al(NO3) Layered Double Hydroxide
Chairul Irawan (a, *), Ayu Ratma Sari (a), Fakhrin Rizaldi (a), Iryanti Fatyasari Nata (a), Meilana Dharma Putra (a)

Department of Chemical Engineering, Faculty of Engineering, Lambung Mangkurat University
Jl. A. Yani Km. 36, Banjarbaru, Kalimantan Selatan, 70714 Indonesia
* cirawan[at]ulm.ac.id


Abstract

Detergent wastewater contains high phosphate concentrations, so that if the wastewater is directly disposed of into a ditch or river then the wastewater can cause water pollution and cause eutrophication. Layered double hydroxides (LDHs) are synthetic materials with positively charged pyruvate type coatings of mixed metal hydroxides by chemical precipitation method. The purpose of this study is to find out the efficiency of phosphate-containing detergent wastewater adsorption using Mg-Al(NO3) LDH. The morphological structure of LDH by the SEM-EDS analysis method shows a loose lamellar structure with a particle size of about 1 μm, and the composition of Mg-Al(NO3) LDH by the XRF analysis method shows that the Mg and Al elements dominate more than other elements. Batch adsorption experimental conducted for detergent wastewater, which is where in this study the phosphate content was of ca. 51.50 mg / L The equilibrium time of the adsorption process using Mg-AL(NO3) LDH is achieved after 60 minutes. The mole ratio of Mg : Al composition of LDH in the adsorption process has slightly affects the decrease in phosphate shown by a mole ratio of 1 : 1, 2 : 1 and 3 : 1 using Mg-Al (NO3) LDH as adsorbent at dose of 1 g, stirring rate of 100 rpm, 60 minutes, and at room temperature that is equal to 4.15 mg/L, 4. 14 mg/L and 4.08 mg/L, respectively. Mg-Al(NO3) LDH is promising an adsorbent for phosphate removal in detergent wastewater.

Keywords: adsorption; detergent wastewater; LDH; phosphate

Topic: Engineering

Link: https://ifory.id/abstract/N67fZECaLuFk

Conference: International Conference on Innovation and Technology (ICIT 2019)

Plain Format | Corresponding Author (Chairul Irawan)

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