Investigation on kinetic and thermodynamic parameters of Cerbera manghas De-Oiled Seed During the pyrolysis process Muzayyin Muzayyin (a), Sukarni Sukarni (b,c*), Retno Wulandari (c)
(a)Master Program of Mechanical Engineering, Graduate School, State University of Malang, Semarang Street 5, Malang 65145, East Java Indonesia, (b)Department of Mechanical Engineering, State University of Malang, Semarang Street 5, Malang 65145, Indonesia (c) Centre of Advanced Materials for Renewable Energy, State University of Malang, Semarang Street 5, Malang 65145, Indonesia *Corresponding author: sukarni.ft[at]um.ac.id
Abstract
The investigation of renewable energy sources is critical regarding the availability of energy in the future. This study was aimed to understand the potential of Cerbera manghas de-oiled seed by investigating the kinetic and thermodynamic parameters during the pyrolysis process. The de-oiled seed was obtained by the pressing of the seed at 33.8192 N/m2 to release its oil content. To find out the decomposition pattern of de-oiled seed, the thermal analyzer (Mettler Toledo TG-DSC1) was occupied where the mass loss of the sample was observed and recorded during the heating process from 25 up to 900 oC with a heating rate of 15 oC/min, and the nitrogen flow rate of 50 mL/min to prevent oxidation during temperature escalation. The kinetic parameters were studied using the Coats-Redfern method. The results showed that the de-oiled seed decomposed into three stages; the first stage occurs at temperatures of 25-178 oC, the second stage occurs at temperatures of 189-488 oC, and the third stage at temperatures of 500-900 oC, with the very low residue of 15.4 % was left over at the final thermal processes. The kinetics analysis resulted in the activation energy, reaction order, and pre-exponential factor of 27.42 kJ/mol, 0.94 and 68,64 min-1, respectively. Following the kinetic results then the thermodynamic parameters were analyzed and resulted in the values of Delta H (Enthalpy), Delta G (Free Gibbs energy), and Delta S (Entropy) that were 22,40 kJ/mol, 171,86 kJ/mol, and -0,2230 kJ/mol, respectively.
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