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The chemical bond is one of the crucial topics in chemistry since it becomes a basic concept to comprehend other topics. Unfortunately, it is hard for students because it is at the microscopic level. This study proposes a way to comprehend that topic by developing a simulation of 3D molecules using Augmented Reality (AR). The data were collected by questionnaire, documentation, and interview. This study was used ADDIE procedure to develop the product. From the results of this study, it can be concluded that the multimedia-based learning media Augmented Reality has very good quality and is worthy of being used as a supporting media in chemical learning activities in the chemical bond topic.