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Effects of Seeding Temperature and Growing Time on the Nanostructural Characteristics of ZnO Nanorods Thin Films prepared by Chemical Bath Deposition
Gerry Resmi Liyana (a*), Akhmad Herman Yuwono (b*)

a) Department of Metallurgical and Materials Engineering, Faculty of Engineering, Universitas Indonesia, Kampus UI Depok, Depok 16424, Indonesia
*gerryliyana[at]gmail.com
b) Department of Metallurgical and Materials Engineering, Faculty of Engineering, Universitas Indonesia, Kampus UI Depok, Depok 16424, Indonesia
*ahyuwono[at]gmail.com


Abstract

ZnO nanostructures have been attracting much interest of researchers due to their unique properties and wide potential for various applications. In this study, the effect of seeding temperature and growing time on the characteristics of ZnO nanorods were investigated. The seed solutions were first prepared at temperature of 0, 30, and 60℃ for 1 hour using zinc nitrate tetrahydrate and hexamethylenetetramine as precursors. The ZnO seed layers were then deposited onto ITO glass substrates by spin coating technique prior to the chemical bath deposition (CBD) growth at temperature of 90℃ for different times (3, 4, and 5 hours). The synthesized ZnO nanorods were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and UV–Vis spectrophotometry. The results showed that with the increase in seeding temperature from 0℃ to 60℃, the crystallite size decreased from 71.32 to 38.95 nm, while the band gap energy increased from 3.27 to 3.55 eV, respectively. While with increased of growing time during CBD, the crystallite size was adversely increased from 65.37 to 88.09 nm, and consequently the band gap energy was found to decrease from 3,55 to 3,52 eV.

Keywords: ZnO nanorods, ITO, chemical bath deposition, seeding temperature, growing time

Topic: Material Engineering

Link: https://ifory.id/abstract/nXJPv7agMWAc

Conference: The 4th Annual Applied Science and Engineering Conference (AASEC 2019)

Plain Format | Corresponding Author (Gerry Resmi Liyana)

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