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This study aims to determine the eligibility of biomolecular e-module that have been developed with discovery learning models on carbohydrate material. The study was conducted at the Chemical Education Study Program, Department of Chemistry, Universitas Negeri Medan. This study uses the ADDIE development model (Analyze, Design, Develop, Implementation, Evaluation). E-module that have been developed are validated by 3 expert lecturers consisting of material expert lecturer, model expert lecturer and expert media lecturer. The instrument used in the study was a questionnaire on Standar Nasional Perguruan Tinggi (SNPT) consisting of content, language, presentation and graphic eligibility. The questionnaire used was validated by an expert validator. The results showed that the biomolecular e-module that had been developed with the discovery learning model on carbohydrate material was valid for college students to use.